WEATHERING AND DETERIORATION OF CARBONATE STONES FROM HISTORICAL MONUMENTS: A REVIEW

Authors

  • Lorena Aliana Cioban Interdisciplinary School of Doctoral Studies, “Aurel Vlaicu” University,
  • Mihaela DOCHIA “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330,
  • Claudia MURESAN “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330
  • Dorina Rodica CHAMBRE “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330, Romania

Keywords:

heritage building, historical monuments, limestone, marble, weathering, deterioration, extrinsic factors

Abstract

The degradation of historical monuments due to atmospheric and anthropogenic factors is a
frequently encountered phenomenon on all continents, being intensively investigated to understand the type
and degree of damage and to choose an appropriate restoration method. Based on extensive
bibliographic documentation, this study presents a comprehensive review of the physical, chemical,
and biological weathering processes induced by extrinsic factors (atmospheric, biological, and
anthropic) that lead to the deterioration of limestone and marble, the most common construction
materials found in historic buildings of humanity's architectural heritage.

Author Biographies

Mihaela DOCHIA, “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330,

Research Development Innovation in Natural and Technical Sciences Institute,

Claudia MURESAN, “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330

Faculty of Food Engineering, Tourism and Environmental Protection

Dorina Rodica CHAMBRE, “Aurel Vlaicu” University, Romania, 2 Elena Dragoi, Arad 310330, Romania

Faculty of Food Engineering, Tourism and Environmental Protection

References

limestone rocks in sculpture as an alternative

to marble: An empirical study. PalArch's Journal of

Archaeology of Egypt / Egyptology 17, 15061-

Aucouturier, M., Darque-Ceretti, E., 2007.

The surface of cultural heritage artefacts:

Physicochemical investigations for their knowledge

and their conservation. Chemical Society reviews

, 1605-1621.

Badouna, I., Koutsovitis, P., Karkalis, C.,

Laskaridis, K., Koukouzas, N., Tyrologou, P.,

Patronis, M., Papatrechas, C., Petrounias, P., 2020.

Petrological and geochemical properties of greek

carbonate stones associated with their physicomechanical

and aesthetic characteristics. Minerals

, 507.

Basu, S., Orr, S.A., Aktas, Y.D., 2020. A

geological perspective on climate change and

building stone deterioration in London:

Implications for urban stone-built heritage research

and management. Atmosphere 11, 788.

Battista, G., de Lieto Vollaro, R., 2017.

Correlation between air pollution and weather data

in urban areas: Assessment of the city of Rome

(Italy) as spatially and temporally independent

regarding pollutants. Atmospheric Environment

, 240-247.

Benavente, D., de Jongh, M., Cañaveras,

J.C., 2021. Weathering Processes and Mechanisms

Caused by Capillary Waters and Pigeon Droppings

on Porous Limestones. Minerals 11, 18.

Bogdan, A., Chambre, D., Copolovici,

D.M., Bungau, T., Bungau, C.C., Copolovici, L.,

Heritage building preservation in the process

of sustainable urban development: The case of

Brasov medieval city, Romania. Sustainability 14,

Bugini, R., Tabasso, M., Realini, M., 2000.

Rate of formation of black crusts on marble. A case

study. Journal of Cultural Heritage - J CULT

HERIT 1, 111-116.Caneva, G., Ceschin, S., 2009. Ecology of

biodeterioration. Plant Biology for Cultural

Heritage. Biodeterioration and Conservation, 35-58.

Cardell, C., Benavente, D., Rodríguez-

Gordillo, J., 2008. Weathering of limestone

building material by mixed sulfate solutions.

Characterization of stone microstructure, reaction

products and decay forms. Materials

Characterization 59, 1371-1385.

Christodoulakis, J., Tzanis, C.G., Varotsos,

C.A., Ferm, M., Tidblad, J., 2017. Impacts of air

pollution and climate on materials in Athens,

Greece. Atmospheric Chemistry and Physics 17,

-448.

Comite, V., Pozo-Antonio, J.S., Cardell, C.,

Rivas, T., Randazzo, L., Russa, M.F.L., Fermo, P.,

a. Environmental impact assessment on the

Monza cathedral (Italy): a multi-analytical

approach.

Comite, V., Ricca, M., Ruffolo, S.A.,

Graziano, S.F., Rovella, N., Rispoli, C., Gallo, C.,

Randazzo, L., Barca, D., Cappelletti, P., La Russa,

M.F., 2020b. Multidisciplinary approach for

evaluating the geochemical degradation of building

stone related to pollution sources in the historical

center of Naples (Italy). Applied Sciences 10, 4241.

Corvo, F., Reyes-Trujeque, J., Valdés, C.,

Villaseñor, F., Cuesta, O., Aguilar, D., Quintana, P.,

Influence of Air Pollution and Humidity on

Limestone Materials Degradation in Historical

Buildings Located in Cities Under Tropical Coastal

Climates. Water Air and Soil Pollution 205, 359-

Cozzolino, A., Adamo, P., Bonanomi, G.,

Motti, R., 2022. The Role of Lichens, Mosses, and

Vascular Plants in the Biodeterioration of Historic

Buildings: A Review. Plants 11, 3429.

Doehne, E., Price, C., 2011. Stone

Conservation: An Overview of Current Research.

Fassina, V., 1988. Environmental pollution in

relation to stone decay. Durability of building

materials 5, 317-358.

Fistos, T., Fierascu, I., Doni, M., Chican,

I.E., Fierascu, R.C., 2022. A short overview of

recent developments in the application of polymeric

materials for the conservation of stone cultural

heritage elements. Materials 15, 6294.

Frank-Kamenetskaya, O., Vlasov, D.,

Zelenskaya, M., Knauf, I., Timasheva, M., 2009.

Decaying of the marble and limestone monuments

in the urban environment. Case studies from Saint

Petersburg, Russia. Studia Universitatis Babes-

Bolyai, Geologia 54.

Gadd, G., 2017. Fungi, Rocks, and

Minerals. Elements 13, 171-176.

Gautam, A., Verma, R., Avasthi, S., Sushma,

Bohra, Y., Devadatha, B., M, N.,

Suwannarach, N., 2022. Current Insight into

Traditional and Modern Methods in Fungal

Diversity Estimates. Journal of Fungi 8, 226.

Graue, B., Siegesmund, S., Oyhantcabal, P.,

Naumann, R., Licha, T., Simon, K., 2013. The

effect of air pollution on stone decay: The decay of

the Drachenfels trachyte in industrial, urban, and

rural environments-a case study of the Cologne,

Altenberg and Xanten cathedrals. Environmental

Earth Sciences 69.

Grossi, C., Brimblecombe, P., 2004.

Aesthetics of Simulated Soiling Patterns on

Architecture. Environmental science & technology

, 3971-3976.

Gulotta, D., Bertoldi, M., Bortolotto, S.,

Fermo, P., Piazzalunga, A., Toniolo, L., 2013. The

Angera stone: A challenging conservation issue in

the polluted environment of Milan (Italy). Environ

Earth Sci 69, 1085-1094.

Hall, K., Hall, A., 1996. Weathering by

wetting and drying: Some experimental results.

Earth Surface Processes and Landforms 21, 365-

Isola, D., Bartoli, F., Meloni, P., Caneva,

G., Zucconi, L., 2022. Black Fungi and Stone

Heritage Conservation: Ecological and Metabolic

Assays for Evaluating Colonization Potential and

Responses to Traditional Biocides. Applied

Sciences 12, 2038.

Ivaskova, M., Kotes, P., Brodnan, M.,

Air pollution as an important factor in

construction materials deterioration in Slovak

Republic. Procedia Engineering 108, 131-138.

Kanani, S., Zandi, H., 2011. A Study of the

Damages to Historical Monuments due to

Climatic Factors and Air Pollution and Offering

Solutions. World Academy of Science, Engineering

and Technology, International Journal of Social,

Behavioral, Educational, Economic, Business and

Industrial Engineering 5, 1018-1021.

Kryza, R., Prell, M., Czechowski, F.,

Domaradzka, M., 2009. Acidic weathering of

carbonate building stones: experimental assessment.

Studia Universitatis Babes-Bolyai, Geologia 54, 33-

La Russa, M.F., Belfiore, C.M., Fichera,

G.V., Maniscalco, R., Calabrò, C., Ruffolo, S.A.,

Pezzino, A., 2015. The behaviour to weathering of

the Hyblean limestone in the Baroque architecture

of the Val di Noto (SE Sicily): An experimental

study on the “calcare a lumachella” stone.

Construction and Building Materials 77, 7-19.

La Russa, M.F., Comite, V., Aly, N., Barca,

D., Fermo, P., Rovella, N., Antonelli, F., Tesser, E.,

Aquino, M., Ruffolo, S.A., 2018. Black crusts on

Venetian built heritage, investigation on the impact

of pollution sources on their composition. The

European Physical Journal Plus 133, 370.

La Russa, M.F., Fermo, P., Comite, V.,

Belfiore, C.M., Barca, D., Cerioni, A., De Santis,

M., Barbagallo, L.F., Ricca, M., Ruffolo, S.A.,

The Oceanus statue of the Fontana di Trevi

(Rome): The analysis of black crust as a tool to

investigate the urban air pollution and its impact on

the stone degradation. Science of The Total

Environment 593-594, 297-309.

Li, Q., Zhang, B., Yang, X., Ge, Q., 2018.

Deterioration-Associated Microbiome of Stone

Monuments: Structure, Variation, and Assembly.

Appl Environ Microbiol 84, e02680-02617.

Liu, X., Qian, Y., Wu, F., Wang, Y., Wang,

W., Gu, J.-D., 2022. Biofilms on stone monuments:

biodeterioration or bioprotection? Trends in

Microbiology 30, 816-819.

Livingston, R.A., 2016. Acid rain attack on

outdoor sculpture in perspective. Atmospheric

Environment 146, 332-345.

Mascaro, M.E., Pellegrino, G., Palermo,

A.M., 2022. Analysis of Biodeteriogens on

Architectural Heritage. An Approach of Applied

Botany on a Gothic Building in Southern Italy.

Sustainability 14, 34.

Matteucci, E., Scarcella, A.V., Croveri, P.,

Marengo, A., Borghi, A., Benelli, C., Hamdan, O.,

Favero-Longo, S.E., 2019. Lichens and other

lithobionts on the carbonate rock surfaces of the

heritage site of the tomb of Lazarus (Palestinian

territories): diversity, biodeterioration, and control

issues in a semi-arid environment. Annals of

Microbiology 69, 1033-1046.

McAlister, J.J., Smith, B.J., Török, A.,

Transition metals and water-soluble ions in

deposits on a building and their potential catalysis

of stone decay. Atmospheric Environment 42,

-7668.

Merrill, S., 2011. Graffiti at Heritage

Places: Vandalism as Cultural Significance or

Conservation Sacrilege? Time and Mind: The

Journal of Archaeology, Consciousness and Culture

, 59-75.

Mineo, S., Caliò, D., Pappalardo, G., 2022.

UAV-Based Photogrammetry and Infrared

Thermography Applied to Rock Mass Survey for

Geomechanical Purposes. Remote Sensing 14, 473.

Oguchi, C.T., Yu, S., 2021. A review of

theoretical salt weathering studies for stone

heritage. Progress in Earth and Planetary Science 8,

Olaru, M., Aflori, M., Simionescu, B.,

Doroftei, F., Stratulat, L., 2010. Effect of SO2 Dry

Deposition on Porous Dolomitic Limestones.

Materials 3, 216-231.

Ortega-Morales, O., Montero-Munoz, J.L.,

Neto, J.A.B., Beech, I.B., Sunner, J., Gaylarde, C.,

Deterioration and microbial colonization of

cultural heritage stone buildings in polluted and

unpolluted tropical and subtropical climates: A

meta-analysis. International Biodeterioration &

Biodegradation 143.

Paiva, D.S., Fernandes, L., Trovão, J.,

Mesquita, N., Tiago, I., Portugal, A., 2022.

Uncovering the Fungal Diversity Colonizing

Limestone Walls of a Forgotten Monument in the

Central Region of Portugal by High-Throughput

Sequencing and Culture-Based Methods. Applied

Sciences 12, 10650.

Pappalardo, G., Mineo, S., Caliò, D.,

Bognandi, A., 2022. Evaluation of Natural Stone

Weathering in Heritage Building by Infrared

Thermography. Heritage 5, 2594-2614.

Pappalardo, G., Mineo, S., Imposa, S.,

Grassi, S., Leotta, A., La Rosa, F., Salerno, D.,

A quick combined approach for the

characterization of a cliff during a post-rockfall

emergency. Landslides 17, 1063-1081.

Pinheiro, A., Mesquita, N., Trovão, J.,

Soares, F., Tiago, I., Coelho, C., Paiva de Carvalho,

H., Gil, F., Catarino, L., Pinar, G., Portugal, A.,

Limestone biodeterioration: A review on the

Portuguese cultural heritage scenario. Journal of

Cultural Heritage 36.

Pozo-Antonio, J.S., Cardell, C., Comite, V.,

Fermo, P., 2022. Characterization of black crusts

developed on historic stones with diverse

mineralogy under different air quality

environments. Environmental Science and Pollution

Research 29, 29438-29454.

Pozo-Antonio, J.S., Cardell, C., Comite, V.,

Fermo, P., 2022. Characterization of black crusts

developed on historic stones with diverse

mineralogy under different air quality

environments. Environmental Science and Pollution

Research 29, 29438-29454.

Pozo-Antonio, J.S., Pereira, M.F.C., Rocha,

C.S.A., 2017. Microscopic characterisation of black

crusts on different substrates. Science of The Total

Environment 584-585, 291-306.Prikryl, R., Melounova, L., Varilova, Z.,

Weishauptova, Z., 2007. Spatial relationships of

salt distribution and related physical changes of

underlying rocks on naturally weathered sandstone

exposures (Bohemian Switzerland National Park,

Czech Republic). Environmental Geology 52, 409-

Reyes-Trujeque, J., Perez, T., Castaneda,

A., Corvo, F., 2010. Role of NOx in material

corrosion and degradation. Revista CENIC.

Ciencias Químicas 41, 1-10.

Reyes-Trujeque, J., Rivera, J., Owen, P.,

Bartolo, P., Perez Lopez, T., Casanova-Gonzalez,

E., Corvo, F., 2016. Weathering effects of an

historic building in San Francisco de Campeche,

Mexico. Intervencion Revista Internacional de

Conservacion Restauracion y Museologia 7, 22-31.

Rodrigues, J., 2015. Defining, mapping and

assessing deterioration patterns in stone

conservation projects. Journal of Cultural Heritage

, 267-275.

Ruffolo, S.A., Comite, V., La Russa, M.F.,

Belfiore, C.M., Barca, D., Bonazza, A., Crisci,

G.M., Pezzino, A., Sabbioni, C., 2015. An analysis

of the black crusts from the Seville Cathedral: A

challenge to deepen the understanding of the

relationships among microstructure, microchemical

features and pollution sources. Science of The Total

Environment 502, 157-166.

Sabbioni, C., Piccolo, D., Bonazza, A.,

Favoni, O., Zappia, G., 2001. Soluble and non

water soluble sulphates in damage layers on

hydraulic mortars. WIT Transactions on the Built

Environment 55, 561-569.

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Published

2023-08-14